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Emanuela Del Gado |
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Università di Napoli |
Abstract
Although gels are ubiquitous in fundamental science, technological
applications and also in our daily life, their structural and dynamical
properties are not well understood.
In contrast to other systems that show a slow relaxation, such as
glass-forming liquids, the structure of gels is given by an open
network that is thought to be responsible for the unusual dynamical
properties of these systems.
I will discuss this issue by means of different models
and recent numerical results.
In particular, I will show that the strong length scale dependence of the
dynamics in gel forming systems turns out to be tightly related to the
formation of the gel structure. The mesh-size of the incipient gel network
may correspond to a crossover length between dramatically different
relaxation processes, from stretched to compressed exponentials.
These features have no analogue in dense glassy systems.
Finally, when the volume fraction is increased in the gelation regime,
the structural relaxation begins to be affected also by the crowding
of the particles, and a crossover to the glassy regime can be found.