Pier Giuseppe GABRIELLI
ENEA Roma
Strength, aging and toughness in strong
glasses
Some brittle materials, like the strong glass SiO2, are very defect-sensitive.
The fracture in these materials, which is due to the ever-present
micro defects, occurs abruptly and without warning. This type of failure
is determined by the loss of stability of a single crack: the deter- mination
of the conditions leading to unstable propagation of single
crack is adressed deter- ministically in fracture
mechanics by investigating the Griffith's
stability of the crack. In strong glasses, which are nonequilibrium
systems,the properties depend on cooling rate with which the sample has
been quenched, so the structure is not statistically homogeneous
and the local stresses may differ from their average values and the
stress threshold at which one microcrack starts propagating
is a random variable. So the problem of the onset of propation
of a crack in strong glasses is intimately connected to the
physics of the elastic objects pinned by random strength. The
determination of the local fracture toughness in strong glasses, where
the microscopic properties are strongly depending on the thermodynamical
history (aging) and on the stress attribuable to the direct interaction
of closely spaced defects, depends almost entirely on the extreme
value statistics of the largest defects. Here we try to connect the
theoretical strenght,the aging effects on mechanical properties and the
local toughness fluctuations in this class of materials.